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A Simple Spectrophotometric Determination of an Equilibrium Constant That Does Not Require Any Measurementsof pH, Mass, Volume, Concentration, or Molar Absorptivity:  The pKaof Methyl Red.
Journal article

A Simple Spectrophotometric Determination of an Equilibrium Constant That Does Not Require Any Measurementsof pH, Mass, Volume, Concentration, or Molar Absorptivity: The pKaof Methyl Red.

David Brown, Terry Dubetz, Patricia D. Barreto and Jose Barreto
The Chemical Educator
09-14-2007

Abstract

Laboratories and Demonstrations general chemistry pKa indicator Equilibrium. Chemistry. Spectrophotometry. Colorimetry.
This laboratory exercise is intended for first-year chemistry students. It is designed to determine the pKa of Methyl Red with good precision and accuracy, while eliminating the need for pH meters, balances, pipets, or multiple buffer solutions. The experimental design is intended to encourage data sharing in class, requires only simple and rapid calculations, and will generate some thought provoking results about the relationship between pH and pKa.
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