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A co-crystal of 1,10-phenanthroline with boric acid:  a novel aza-aromatic complex
Journal article   Peer reviewed

A co-crystal of 1,10-phenanthroline with boric acid: a novel aza-aromatic complex

Arsalan Mirjafari, Lam Pham, Philip J. Smith, Richard E. Sykora and James H. Davis
Acta Crystallographica Section E Structure Reports Online, Vol.69(7), p.o1067
07-15-2013
PMID: 24627684

Abstract

hydrogen-bonded cyclic crystal stability boric acid
Excerpt: The title compound, C12H8N2·2B(OH)3, is best described as a host-guest complex in which the B(OH)3 mol-ecules form a hydrogen-bonded cyclic network of layers parallel to the ab plane into which the 1,10-phenanthroline mol-ecules are bound. An extensive network of hydrogen bonds are responsible for the crystal stability. No π-stacking inter-actions occur between the 1,10-phenanthroline mol-ecules.
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