An asymmetric, bifunctional catalytic approach to non-natural [alpha]-amino acid derivatives
Daniel H Paull, Ethan Alden-Danforth, Jamison Wolfer, Cajetan Dogo-Isonagie, Ciby J Abraham and Thomas Leetka
Journal of organic chemistry, Vol.72(14), p.5380
07-06-2007
Abstract
Amino acids Analysis Chemical properties Chemical synthesis
A catalytic, asymmetric process for the synthesis of 1,4-benzoxazinones from o-benzoquinone imides and ketene enolates in presence of cocatalyst Sc[(OTf).sub.3] which increased the yield by 42% is reported.
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Title
An asymmetric, bifunctional catalytic approach to non-natural [alpha]-amino acid derivatives