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Click chemistry mediated synthesis of bio-inspired phosphonyl-functionalized ionic liquids
Journal article   Peer reviewed

Click chemistry mediated synthesis of bio-inspired phosphonyl-functionalized ionic liquids

Richard A. Braun, Joseph L. Bradfield, Codey B. Henderson, Niloufar Mobarrez, Yinghong Sheng, Richard A. O'Brien, Alexandra C. Stenson, James H. Davis and Arsalan Mirjafari
Green chemistry : an international journal and green chemistry resource : GC, Vol.17(2), pp.1259-1268
01-01-2015

Abstract

Chemistry Chemistry, Multidisciplinary Green & Sustainable Science & Technology Physical Sciences Science & Technology Science & Technology - Other Topics
This study focuses on the synthesis of a class of novel biologically-inspired ionic liquids coupled with a phosphonate group containing short to long side chains (C-3-C-11) via the Pudovic reaction. The ionic liquids exhibited very low glass transition temperatures and were hydrophobic in character. This method has the attributes of "click" chemistry with outstanding efficiency, simplicity, yields and regioselectivity. The results of their calcium(II) ligating capability are also presented.

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