Crystal structure of a methimazole-based ionic liquid

Jamie C. Gaitor; Manuel Sanchez Zayas; Darrel J. Myrthil; Frankie White; Jeffrey M. Hendrich; Richard E. Sykora; Richard A. O'Brien; John T. Reilly; Arsalan Mirjafari

doi:10.1107/S2056989015022136

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Crystal structure of a methimazole-based ionic liquid

Journal article

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Crystal structure of a methimazole-based ionic liquid

Jamie C. Gaitor, Manuel Sanchez Zayas, Darrel J. Myrthil, Frankie White, Jeffrey M. Hendrich, Richard E. Sykora, Richard A. O'Brien, John T. Reilly and Arsalan Mirjafari

Acta Crystallographica Section E Crystallographic Communications, Vol.71(12), p.o1008

12-01-2015

DOI: https://doi.org/10.1107/S2056989015022136

PMID: 26870468

Appears in United Nations Sustainable Development Goals @ FGCU

Abstract

crystal structure

ionic liquids

methimazole

S-allylation

nitrogen heterocycle

Excerpt: The structure of 1-methyl-2-(prop-2-en-1-ylsulfanyl)-1H- imidazol-3-ium bromide, C7H11N2S+􏰀Br􏰁, has monoclinic (P21/c) symmetry. In the crystal, the components are linked by N—H􏰀􏰀􏰀Br and C—H􏰀􏰀􏰀Br hydrogen bonds. The crystal structure of the title compound undeniably proves that methimazole reacts through the thione tautomer, rather than the thiol tautomer in this system.

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Title: Crystal structure of a methimazole-based ionic liquid
Creators: Jamie C. Gaitor (Author) - Florida Gulf Coast University
Manuel Sanchez Zayas (Author) - Florida Gulf Coast University
Darrel J. Myrthil (Author) - Florida Gulf Coast University
Frankie White (Author) - University of South Alabama
Jeffrey M. Hendrich (Author) - University of South Alabama
Richard E. Sykora (Author) - University of South Alabama
Richard A. O'Brien (Author) - Department of Chemistry & Physics
John T. Reilly (Author) - Florida Gulf Coast University
Arsalan Mirjafari (Author) - Florida Gulf Coast University
Publication Details: Acta Crystallographica Section E Crystallographic Communications, Vol.71(12), p.o1008
Publisher: INT UNION CRYSTALLOGRAPHY
Format: text
Number of pages: 7
Grant note: Alice and Karl Sheffield ScholarshipDepartment of Chemistry and Physics of FGCUNational Science Foundation (NSF-CAREER): CHE-0846680
The authors thank the Alice and Karl Sheffield Scholarship and the Department of Chemistry and Physics of FGCU for funding this project. They also acknowledge the National Science Foundation for their generous support (NSF-CAREER grant to RES, CHE-0846680).
Identifiers: fgcu_ir_000082; 99383341631706570
Academic Unit: Department of Chemistry & Physics
Language: English
Resource Type: Journal article

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Crystal structure of a methimazole-based ionic liquid

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