Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate

Joseph L. Bradfield; Richard A. Braun; Frankie White; Jeffrey M. Hendrich; Richard E. Sykora; Arsalan Mirjafari

doi:10.1107/S1600536814021357

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Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate

Journal article

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Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate

Joseph L. Bradfield, Richard A. Braun, Frankie White, Jeffrey M. Hendrich, Richard E. Sykora and Arsalan Mirjafari

Acta Crystallographica Section E Structure Reports Online, Vol.70(10), p.o1143

10-01-2014

DOI: https://doi.org/10.1107/S1600536814021357

PMID: 25484719

Appears in United Nations Sustainable Development Goals @ FGCU

Abstract

crystal structure

ionic salt

vinyltriphenylphosphonium

tetra- phenylborate.

The title ionic salt, C21H20P+􏰀C24H20B􏰁, crystallized with two independent vinyltriphenylphosphonium cations and two independent tetraphenylborate anions per asymmetric unit. These four independent moieties contain nearly perfect tetrahedral symmetry about their respective central C atoms. In the crystal, there are no 􏰄-stacking or other intermolecular interactions present.

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Title: Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate
Creators: Joseph L. Bradfield (Author) - Florida Gulf Coast University
Richard A. Braun (Author) - Florida Gulf Coast University
Frankie White (Author) - University of South Alabama
Jeffrey M. Hendrich (Author) - University of South Alabama
Richard E. Sykora (Author) - University of South Alabama
Arsalan Mirjafari (Author) - Florida Gulf Coast University
Publication Details: Acta Crystallographica Section E Structure Reports Online, Vol.70(10), p.o1143
Publisher: INT UNION CRYSTALLOGRAPHY
Format: text
Number of pages: 15
Grant note: Department of Chemistry and Physics of FGCUNational Science FoundationNSF-CAREER: CHE0846680
The authors are grateful to the Department of Chemistry and Physics of FGCU for the financial support of this work. They also acknowledge the National Science Foundation for their generous support (NSF-CAREER grant to RES, CHE0846680).
Identifiers: fgcu_ir_000075; 99383341683406570
Academic Unit: Department of Chemistry & Physics
Language: English
Resource Type: Journal article

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Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate

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