Functionalized ionic liquids with highly polar polyhydroxylated appendages and their rapid synthesis via thiol-ene click chemistry

Richard A O’Brien; Arsalan Mirjafari; Vijayakumari Jajam; Erin N Capley; Alexandra C Stenson; Kevin N West; James H Davis

doi:10.1016/j.tetlet.2011.07.126

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Functionalized ionic liquids with highly polar polyhydroxylated appendages and their rapid synthesis via thiol-ene click chemistry

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Functionalized ionic liquids with highly polar polyhydroxylated appendages and their rapid synthesis via thiol-ene click chemistry

Richard A O’Brien, Arsalan Mirjafari, Vijayakumari Jajam, Erin N Capley, Alexandra C Stenson, Kevin N West and James H Davis

Tetrahedron letters, Vol.52(40), pp.5173-5175

2011

DOI: https://doi.org/10.1016/j.tetlet.2011.07.126

Abstract

The thiol-ene ‘click’ reaction of 1-thioglycerol with ionic liquids incorporating cations bearing appended vinyl- and/or allyl groups is a versatile, single-step means for their conversion into derivatives bearing up to eight hydroxyl groups per cation.

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Title: Functionalized ionic liquids with highly polar polyhydroxylated appendages and their rapid synthesis via thiol-ene click chemistry
Creators: Richard A O’Brien - University of South Alabama
Arsalan Mirjafari - University of South Alabama
Vijayakumari Jajam - University of South Alabama
Erin N Capley - University of South Alabama
Alexandra C Stenson - University of South Alabama
Kevin N West - University of South Alabama
James H Davis - University of South Alabama
Publication Details: Tetrahedron letters, Vol.52(40), pp.5173-5175
Publisher: Elsevier Ltd; OXFORD
Number of pages: 3
Grant note: ChevronNational Science Foundation: 1039944 Division Of Chemistry; Direct For Mathematical & Physical Scien: 1039944 Div Of Chem, Bioeng, Env, & Transp Sys; Directorate For Engineering: 1133101
J.H.D. and K.N.W. thank Chevron for partial support of this work. A.C.S. and J.H.D. thank the National Science Foundation for an MRI Grant (1039944) used to purchase the linear ion trap mass spectrometer used in this work.
Identifiers: 99383437299606570
Academic Unit: Department of Chemistry & Physics
Language: English
Resource Type: Journal article

Functionalized ionic liquids with highly polar polyhydroxylated appendages and their rapid synthesis via thiol-ene click chemistry

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