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Microwave-Promoted, One-Pot Conversion of Alkoxymethylated Protected Alcohols into Their Corresponding Nitriles, Bromides, and Iodides Using [bmim][InCl4] as a Green Catalyst
Journal article

Microwave-Promoted, One-Pot Conversion of Alkoxymethylated Protected Alcohols into Their Corresponding Nitriles, Bromides, and Iodides Using [bmim][InCl4] as a Green Catalyst

Arsalan Mirjafari, Iraj Mohammadpoor-Baltork, Majid Moghadam, Shahram Tangestaninejad, Valiollah Mirkhani and Ahmad Reza Khosropour
ChemInform, Vol.41(41), pp.no-no
10-12-2010

Abstract

halogen compounds (benzene compounds) mechanochemistry microwave chemistry nitriles (acyclic compounds) nitriles (benzene compounds) sonochemistry
The Lewis acid room temperature ionic liquid, [bmim][InCl4], was found to be an efficient and green catalyst for the highly chemoselective and one-pot conversion of MOM- or EOM-ethers into their corresponding nitriles, bromides, and iodides under microwave irradiation. The procedures are simple, rapid, and high yielding. The catalyst exhibited a remarkable reactivity and is reusable.
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