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Radiation synthesis, characterization and amidoximation of N-vinyl-2-pyrrolidone/acrylonitrile interpenetrating polymer networks
Journal article   Peer reviewed

Radiation synthesis, characterization and amidoximation of N-vinyl-2-pyrrolidone/acrylonitrile interpenetrating polymer networks

Nurettin Sahiner, Nursel Pekel and Olgun Güven
Reactive & functional polymers, Vol.39(2), pp.139-146
02-15-1999

Abstract

60Co-γ rays Amidoximation FT-IR and TGA Interpenetrating polymer networks
Interpenetrating polymer networks (IPNs) were synthesized by irradiating acrylonitrile solutions of poly(N-vinyl-2-pyrrolidone) with 60Co-γ rays. The conversion to insoluble IPN structure was characterized using FT-IR and thermal analysis methods. The amidoximation of polyacrylonitrile moieties of IPN was carried out in aqueous solutions of NH2OH·HCl–NaOH at 50°C. The conversion of amidoximation was followed by using FT-IR spectrophotometer and conversion of nitrile groups to amidoxime was determined as percentage. The structure of amidoximated IPN was characterized by FT-IR and thermal methods as well.
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