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Two corrugated 2D bilayer (6(3))(6(5)8) topological coordination polymers: Synthesis, structure, and water-induced reversible transformation
Journal article   Peer reviewed

Two corrugated 2D bilayer (6(3))(6(5)8) topological coordination polymers: Synthesis, structure, and water-induced reversible transformation

Yunxia Hu, Wenwei Zhang, Xiaofei Zhang, Zhilin Wang, Yizhi Li and Junfeng Bai
Inorganic chemistry communications, Vol.12(2), pp.166-168
02-01-2009
DOI: https://doi.org/10.1016/j.inoche.2008.12.005

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
Two stable supramolecular microporous polymers with double-layer structures, [Co(AIP) (BPY)(0.5) center dot H2O](n)center dot 2nH(2)O (1) and [Ni(AIP)(BPY)(0.5) center dot H2O](n) center dot 2nH(2)O (2), were constructed from AIP (5-aminoisophthalate) and BPY (4,4'-bipyridine) under hydrothermal conditions. Both of them exhibit rarely reported (3,4)-connected (6(3))(6(5)8) topology and interesting water-induced reversible transformation properties that are confirmed by PXRD studies. (c) 2008 Elsevier B.V. All rights reserved.

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