Abstract
Atmospheric carbon dioxide (CO (sub 2) ) is absorbed by the ocean's surface where it combines with seawater to form a weak, naturally occurring acid called carbonic acid (H (sub 2) CO (sub 3) ). Increasing carbon dioxide in the atmosphere results in the absorption of more CO (sub 2) by the ocean and, therefore, increases in the acidity of seawater. This process, known as ocean acidification, has the potential to elicit change in ecosystems and organisms by disrupting biological processes. For example, ocean acidification is a problem for marine organisms such as corals, foraminifera, and algae that precipitate calcium carbonate to form their skeletons and shells (Kleypas and others, 2006). The effects are related to corresponding changes in the carbonate saturation state (Omega ), where Omega is the ratio of the ion concentration product (Ca (super 2+) X CO (sub 3) (super 2-) ) to the stoichiometric aragonite solubility product (K*sp) (Langdon and Atkinson, 2005). Because pH and CO (sub 3) (super 2-) are strongly interdependent through the inorganic carbon system, the decrease in pH will cause a proportionally greater decrease in CO (sub 3) (super 2-) . Globally, ocean acidification is occurring faster than at any time in the last 300 million years (Broeker and others, 1979). Recent evidence indicates that individual oceans are responding at different rates, depending on physical and biological processes. For example in the Arctic Ocean, the rate of saturation state decrease was 2.1 percent per year between 1997 and 2010 (Robbins and others., 2013) in an area as large as Montana, largely because of increases in melt of ice, versus the average rate observed for the Pacific Ocean (0.36 percent per year) (Feely and others, 2012). Unfortunately, comparative data sets over multiyear time frames are often not available because time series baseline carbon information has not been collected in many oceans. Data are needed in subtropical latitudes where carbonate saturation states are already naturally low and fluctuate seasonally. These data will help construct a baseline for the assessment of future changes.